A Bio‐Inspired and Biomass‐Derived Healable Photochromic Material Induced by Hierarchical Structural Design

Utilization of bionics to develop stimuli responsive polymers that can heal damage with excellent restorability is particularly attractive for a sustainable society. Herein, inspired by chameleons, a hierarchical structural design strategy is proposed and illustrated to fabricate a healable photochromic material based on a self‐healable polymeric matrix and a finely dispersed photochromic spirooxazine. The self‐healable polymeric matrix is fabricated via the integration of multiple hydrogen bonds (H bonds) and covalent cross‐links into a biomass‐derived elastomer. The dynamic nature and soft characteristics enable the as‐prepared elastomer superior extensibility as well as self‐healing ability, while the covalent cross‐links can assist the reassociation of ruptured H bonds. The representative elastomer exhibits an extensibility of 2600% and toughness of 42.76 MJ m^?3. Furthermore, it shows good self‐healing ability with complete recovery of scratch as well as restoration against 1900% of elongation and 24.1 MJ m^?3 of toughness after healing at 60 °C for 24 h. This combination of moderate toughness, good self‐healing ability, and smart photochromic property in biomass‐derived materials should largely improve their applicability, reliability, and sustainability in various materials and devices.     

强变形工艺对2519A铝合金组织与性能的影响

通过硬度测试、拉伸性能测试、透射电镜观察等分析手段研究了不同强变形工艺下2519A铝合金的力学性能与微观组织。结果表明,经50%的冷轧变形和165 ℃人工时效后,2519A合金的力学性能明显提高,其抗拉强度、屈服强度和伸长率分别为522 MPa、468 MPa和8.5%。而在冷变形前添加165 ℃×2 h预时效处理,合金的力学性能进一步提高,其抗拉强度、屈服强度和伸长率分别达到535 MPa、497 MPa和8%。预时效处理可以提高合金中θ′相的密度,使析出相分布更加均匀,有助于提高合金的力学性能。     

金帆奖体育类获奖节目的后期制作简析

金帆奖是我国电视技术质量方面的最高奖项,设置该奖项的目的是提高电视节目的技术质量,加强电视节目技术质量的规范化管理,促进电视节目制作和播出人员业务水平不断提高。本文主要从视频剪辑、音效与字幕制作、色彩校正这三个方面详细介绍浙江广播电视集团金帆奖体育类获奖节目的后期制作思路、遇到的问题及解决方法,在实践中获得的心得体会与大家分享,进一步凸显出高清节目后期制作时节目质量控制的重要性。     

Unveiling the role of Fe3O4in polymer spin valve near Verwey transition

The spinterface formed between ferromagnetic(FM)electrode and organic materials is vital for performance optimization in organic spin valve(OSV).Half-metallic Fe₃O₄with drastic change in structure,conductivity and magnetic property near Verwey transition can serve as an intrinsic spinterface regulator.However,such modulating effect of Fe₃O₄in OSV has not been comprehensively investigated,especially below the Verwey transition temperature(Tv).Here,we highlight the important role of Fe₃O₄electrode in reliable-working and controllable Fe₃O₄/P3HT/Co polymer spin valves by investigating the magnetoresistance(MR)above and below 7V.In order to distinguish between different contributions to charge transport and related MR responses,the systematic electronic and magnetic characterizations were carried out in full temperature range.Particularly,the first-order metal-insulator transition in Fe₃O₄has a dramatic effect on the MR enhancement of polymer spin valves at 7V.Moreover,both the conducting mode transformation and MR line shape modulation could be accomplished across 7V.This research renders unique scenario to multimodal storage by external thermodynamic parameters,and further reveals the importance of spin-dependent interfacial modification in polymer spin valves.     

用于远程激光测距机的板条激光器

研制了用于远程激光脉冲测距机的板条激光器。使用半导体泵浦的MOPA激光结构实现了大于250 mJ的脉冲激光输出,输出脉冲宽度为12.83 ns,最终输出激光光束束散角为0.18 mrad。该激光测照器可应用于远程激光测距。对激光测距机的测距与照射能力进行了理论计算与分析。理论分析表明,应用于机载平台时,该激光测照器能够实现50 km距离的激光测距。该型激光测距机具有测距距离远,重量轻,结构紧凑等特点,具有广泛的应用前景。     

Continuous Flow Fabrication of Block Copolymer–Grafted Silica Micro‐Particles in Environmentally Friendly Water/Ethanol Media

Polymer‐grafted inorganic particles (PGIPs) are attractive building blocks for numerous chemical and material applications. Surface‐initiated controlled radical polymerization (SI‐CRP) is the most feasible method to fabricate PGIPs. However, a conventional in‐batch reaction still suffers from several disadvantages, including time‐consuming purification processes, low grafting efficiency, and possible gelation problems. Herein, a facile method is demonstrated to synthesize block copolymer–grafted inorganic particles, that is, poly(poly(ethylene glycol) methyl ether methacrylate) (PPEGMEMA)‐b‐poly(N‐isopropylacrylamide) (PNIPAM)–grafted silica micro‐particles using continuous flow chemistry in an environmentally friendly aqueous media. Immobilizing the chain transfer agent and subsequent SI‐CRP can be accomplished sequentially in a continuous flow system, avoiding multi‐step purification processes in between. The chain length (MW) of the grafted polymers is tunable by adjusting the flow time or monomer concentration, and the narrower molar mass dispersity (Р< 1.4) of the grafted polymers reveals the uniform polymer chains on the particles. Moreover, compared with the in‐batch reaction at the same condition, the continuous system also suppresses possible gelation problems.